Regiodivergent and Stereoselective Hydrosilylation of 1,3-Disubstituted Allenes.

نویسندگان

  • Zachary D Miller
  • Ruth Dorel
  • John Montgomery
چکیده

Methods for the highly stereoselective and regiodivergent hydrosilylation of 1,3-disubstituted allenes have been developed. The synthesis of E allylsilanes is accomplished with palladium NHC catalysts, and trisubstituted Z alkenylsilanes are accessed with nickel NHC catalysts. Unsymmetrically substituted allenes are well tolerated with nickel catalysis and afford Z alkenylsilanes. Evidence for a plausible mechanism was obtained through an isotopic double-labeling crossover study.

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عنوان ژورنال:
  • Angewandte Chemie

دوره 54 31  شماره 

صفحات  -

تاریخ انتشار 2015